Not done this yet myself, but a quick bit of Google-Fu reveals a tech tip on blogs.oracle.com with examples of exactly what you ask for.
Example taken from the blog post:
MultivaluedMap formData = new MultivaluedMapImpl();
formData.add("name1", "val1");
formData.add("name2", "val2");
ClientResponse response = webResource
.type(MediaType.APPLICATION_FORM_URLENCODED_TYPE)
.post(ClientResponse.class, formData);
That any help?
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