I did this in sniproxy, examining a TLS client hello packet in Wireshark while reading that RFC is a pretty good way to go. It's not too hard, just lots of variable length fields you have to skip past and check checking if you have the correct element type.
I'm working on my tests right now, and have this annotated sample packet that might help:
const unsigned char good_data_2[] = {
// TLS record
0x16, // Content Type: Handshake
0x03, 0x01, // Version: TLS 1.0
0x00, 0x6c, // Length (use for bounds checking)
// Handshake
0x01, // Handshake Type: Client Hello
0x00, 0x00, 0x68, // Length (use for bounds checking)
0x03, 0x03, // Version: TLS 1.2
// Random (32 bytes fixed length)
0xb6, 0xb2, 0x6a, 0xfb, 0x55, 0x5e, 0x03, 0xd5,
0x65, 0xa3, 0x6a, 0xf0, 0x5e, 0xa5, 0x43, 0x02,
0x93, 0xb9, 0x59, 0xa7, 0x54, 0xc3, 0xdd, 0x78,
0x57, 0x58, 0x34, 0xc5, 0x82, 0xfd, 0x53, 0xd1,
0x00, // Session ID Length (skip past this much)
0x00, 0x04, // Cipher Suites Length (skip past this much)
0x00, 0x01, // NULL-MD5
0x00, 0xff, // RENEGOTIATION INFO SCSV
0x01, // Compression Methods Length (skip past this much)
0x00, // NULL
0x00, 0x3b, // Extensions Length (use for bounds checking)
// Extension
0x00, 0x00, // Extension Type: Server Name (check extension type)
0x00, 0x0e, // Length (use for bounds checking)
0x00, 0x0c, // Server Name Indication Length
0x00, // Server Name Type: host_name (check server name type)
0x00, 0x09, // Length (length of your data)
// "localhost" (data your after)
0x6c, 0x6f, 0x63, 0x61, 0x6c, 0x68, 0x6f, 0x73, 0x74,
// Extension
0x00, 0x0d, // Extension Type: Signature Algorithms (check extension type)
0x00, 0x20, // Length (skip past since this is the wrong extension)
// Data
0x00, 0x1e, 0x06, 0x01, 0x06, 0x02, 0x06, 0x03,
0x05, 0x01, 0x05, 0x02, 0x05, 0x03, 0x04, 0x01,
0x04, 0x02, 0x04, 0x03, 0x03, 0x01, 0x03, 0x02,
0x03, 0x03, 0x02, 0x01, 0x02, 0x02, 0x02, 0x03,
// Extension
0x00, 0x0f, // Extension Type: Heart Beat (check extension type)
0x00, 0x01, // Length (skip past since this is the wrong extension)
0x01 // Mode: Peer allows to send requests
};