This is how it should be done... use dt.round
df.assign(Date=df.Date.dt.round('H'))
Date Num
0 2011-01-01 00:00:00 0.577957
1 2011-01-01 01:00:00 0.995748
2 2011-01-01 02:00:00 0.864013
3 2011-01-01 03:00:00 0.468762
4 2011-01-01 04:00:00 0.866827
OLD ANSWER
One approach is to set the index and use resample
df.set_index('Date').resample('H').last().reset_index()
Date Num
0 2011-01-01 00:00:00 0.577957
1 2011-01-01 01:00:00 0.995748
2 2011-01-01 02:00:00 0.864013
3 2011-01-01 03:00:00 0.468762
4 2011-01-01 04:00:00 0.866827
Another alternative is to strip the date
and hour
components
df.assign(
Date=pd.to_datetime(df.Date.dt.date) +
pd.to_timedelta(df.Date.dt.hour, unit='H'))
Date Num
0 2011-01-01 00:00:00 0.577957
1 2011-01-01 01:00:00 0.995748
2 2011-01-01 02:00:00 0.864013
3 2011-01-01 03:00:00 0.468762
4 2011-01-01 04:00:00 0.866827
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