Given what I think you're trying to get, this should do it:
SET DATEFIRST 1
DECLARE
@start_date DATETIME,
@end_date DATETIME
SET @start_date = '2011-07-11'
SET @end_date = '2011-07-22'
;WITH Days_Of_The_Week AS (
SELECT 1 AS day_number, 'Monday' AS day_name UNION ALL
SELECT 2 AS day_number, 'Tuesday' AS day_name UNION ALL
SELECT 3 AS day_number, 'Wednesday' AS day_name UNION ALL
SELECT 4 AS day_number, 'Thursday' AS day_name UNION ALL
SELECT 5 AS day_number, 'Friday' AS day_name UNION ALL
SELECT 6 AS day_number, 'Saturday' AS day_name UNION ALL
SELECT 7 AS day_number, 'Sunday' AS day_name
)
SELECT
day_name,
1 + DATEDIFF(wk, @start_date, @end_date) -
CASE WHEN DATEPART(weekday, @start_date) > day_number THEN 1 ELSE 0 END -
CASE WHEN DATEPART(weekday, @end_date) < day_number THEN 1 ELSE 0 END
FROM
Days_Of_The_Week
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