I had the same problem.
It happened because I had a mistake with the 'Native library location' configuration:
Goto Eclipse -> Window -> Preferences:
Goto User Libraries:
Make sure that your native library location path is (change c:/opencv-2.4.9 to your own opencv folder):
C:/opencv-2.4.9/build/java/x64
and not:
C:/opencv-2.4.9/build/x64
(I missed the /java folder...)
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