A CFG grammar is non-deterministic, meaning that some input could result in two or more possible parse-trees. Though most CFG-based parser-generators have restrictions on the determinability of the grammar. It will give a warning or error if it has two or more choices.
A PEG grammar is deterministic, meaning that any input can only be parsed one way.
To take a classic example; The grammar
if_statement := "if" "(" expr ")" statement "else" statement
| "if" "(" expr ")" statement;
applied to the input
if (x1) if (x2) y1 else y2
could either be parsed as
if_statement(x1, if_statement(x2, y1, y2))
or
if_statement(x1, if_statement(x2, y1), y2)
A CFG-parser would generate a Shift/Reduce-conflict, since it can't decide if it should shift (read another token), or reduce (complete the node), when reaching the "else" keyword. Of course, there are ways to get around this problem.
A PEG-parser would always pick the first choice.
Which one is better is for you to decide. My opinion is that often PEG-grammars is easier to write, and CFG grammars easier to analyze.
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