In general no. Since Python 3.7 the order is determined by the order of key insertion. So only if the two dictionaries had the same order of key insertion would this be true.
However, you can easily use list comprehensions to create corresponding lists.
Code
# actual - name of actual dictionary
# predicted - name of predicted dictionary
# We create two lists which are in sync as (works since we are constructing
# both list based upon ther order keys in dictionary actual
actual_values = [v for _, v in actual.items()]
predicted_values = [predicted[k] for k, _ in actual.items()]
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