As always, remember that storing non-scalar objects in frames is generally disfavoured, and should really only be used as a temporary intermediate step.
That said, you can use the .str
accessor even though it's not a column of strings:
>>> df = pd.DataFrame({"A": [[1,2],[3,4],[8,9],[2,6]]})
>>> df["new_col"] = df["A"].str[0]
>>> df
A new_col
0 [1, 2] 1
1 [3, 4] 3
2 [8, 9] 8
3 [2, 6] 2
>>> df["new_col"]
0 1
1 3
2 8
3 2
Name: new_col, dtype: int64
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