It looks like S3 doesn't apply any normalization itself. If I upload (using the S3 web console) a file with a unicode name (eg A?rende.txt) to S3 from a Mac and again from Windows, I'll end up with two files in S3. They look the same in the S3 console, but they are considered distinct by S3 because the encoding of the name is different.
You will have to consider exactly how it affects your application (users) and adjust accordingly. For example, if your users may switch between environments (Mac vs Windows vs Linux) and expect consistent cross-platform behaviour, then it seems you will need to normalize the names yourself. If your users work from a single platform consistently, then you wouldn't need to care most likely.
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