No, it's not possible. Since SPI is 4- wire interface. The SS line is used for slave selection.One SPI master can have multiple slaves but it cannot select all the slaves at once since it is either using some bit or SS signal to select the slave(and cannot select multiple slave at a single time).
SPI works in full duplex mode(most of time and cases), and is implemented using shift registers. Hence while writing the data on MOSI(assumption: master is writing),we are getting the data in MISO line too (inserting data in master shift register does shift the data in slave shift register). Hence we get data on both of the TX and RX lines.
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