First check if your command line recognizes mysql command. If not go to command & type in:
set path=c:wampinmysqlmysql5.1.36in
Then use this command to export your database:
mysqldump -u YourUser -p YourDatabaseName > wantedsqlfile.sql
You will then be prompted for the database password.
This exports the database to the path you are currently in, while executing this command
Note: Here are some detailed instructions regarding both import and export
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