If you're doing assembly programming under Windows you don't do manual syscalls. You use NTDLL and the Native API to do that for you.
The Native API is simply a wrapper around the kernelmode side of things. All it does is perform a syscall for the correct API.
You should NEVER need to manually syscall so your entire question is redundant.
Linux syscall codes do not change, Windows's do, that's why you need to work through an extra abstraction layer (aka NTDLL).
EDIT:
Also, even if you're working at the assembly level, you still have full access to the Win32 API, there's no reason to be using the NT API to begin with! Imports, exports, etc all work just fine in assembly programs.
EDIT2:
If you REALLY want to do manual syscalls, you're going to need to reverse NTDLL for each relevant Windows version, add version detection (via the PEB), and perform a syscall lookup for each call.
However, that would be silly. NTDLL is there for a reason.
People have already done the reverse-engineering part: see https://j00ru.vexillium.org/syscalls/nt/64/ for a table of system-call numbers for each Windows kernel. (Note that the later rows do change even between versions of Windows 10.) Again, this is a bad idea outside of personal-use-only experiments on your own machine to learn more about asm and/or Windows internals. Don't inline system calls into code that you distribute to anyone else.
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