I explored on the net and got the answer to my question that how one can forward a call programmatically. Add these lines of code and one will be able to achieve it.
String callForwardString = "**21*1234567890#";
Intent intentCallForward = new Intent(Intent.ACTION_DIAL); // ACTION_CALL
Uri uri2 = Uri.fromParts("tel", callForwardString, "#");
intentCallForward.setData(uri2);
startActivity(intentCallForward);
Here 1234567890 represents the phone number. Add the approriate phone number as you wish here. One can dial ##21# to deactivate the service.
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