If you want to use list comprehension, there's a great answer here:
https://stackoverflow.com/a/3197365/4403872
In your case, it would be like this:
result = [dict(item, **{'elem':'value'}) for item in myList]
Eg.:
myList = [{'a': 'A'}, {'b': 'B'}, {'c': 'C', 'cc': 'CC'}]
Then use either
result = [dict(item, **{'elem':'value'}) for item in myList]
or
result = [dict(item, elem='value') for item in myList]
Finally,
>>> result
[{'a': 'A', 'elem': 'value'},
{'b': 'B', 'elem': 'value'},
{'c': 'C', 'cc': 'CC', 'elem': 'value'}]
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