from collections import Counter
print [item for items, c in Counter(a).most_common() for item in [items] * c]
# [5, 5, 5, 5, 3, 3, 3, 4, 4, 4, 1, 1, 2]
Or even better (efficient) implementation
from collections import Counter
from itertools import repeat, chain
print list(chain.from_iterable(repeat(i, c) for i,c in Counter(a).most_common()))
# [5, 5, 5, 5, 3, 3, 3, 4, 4, 4, 1, 1, 2]
Or
from collections import Counter
print sorted(a, key=Counter(a).get, reverse=True)
# [5, 5, 5, 5, 3, 3, 3, 4, 4, 4, 1, 1, 2]
If you prefer in-place sort
a.sort(key=Counter(a).get, reverse=True)