You can use Convert.ToSByte
For example:
string x = "aa";
sbyte v = Convert.ToSByte(x, 16);
// result: v = 0xAA or -86
You can also use sbyte.Parse
For example:
string y = "bb";
sbyte w = sbyte.Parse(y, System.Globalization.NumberStyles.HexNumber);
// result: w = 0xBB or -69
To answer your question about the upper or lower byte of an Int16:
string signed_short = "feff";
// Truncate 16 bit value down to 8 bit
sbyte b1 = (sbyte)Convert.ToInt16(signed_short, 16);
sbyte b2 = (sbyte)short.Parse(signed_short, System.Globalization.NumberStyles.HexNumber);
// result: b1 = 0xFF or -1
// result: b2 = 0xFF or -1
// Use upper 8 bit of 16 bit
sbyte b3 = (sbyte)(Convert.ToInt16(signed_short, 16) >> 8);
sbyte b4 = (sbyte)(short.Parse(signed_short, System.Globalization.NumberStyles.HexNumber) >> 8);
// result: b3 = 0xFE or -2
// result: b4 = 0xFE or -2
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