Unfortunately, OpenCV doesn't provide any sort of indication as to the color space in the IplImage structure, so if you blindly pick up an IplImage from somewhere there is just no way to know how it was encoded. Furthermore, no algorithm can definitively tell you if an image should be interpreted as HSV vs. RGB - it's all just a bunch of bytes to the machine (should this be HSV or RGB?). I recommend you wrap your IplImages in another struct (or even a C++ class with templates!) to help you keep track of this information. If you're really desperate and you're dealing only with a certain type of images (outdoor scenes, offices, faces, etc.) you could try computing some statistics on your images (e.g. build histogram statistics for natural RGB images and some for natural HSV images), and then try to classify your totally unknown image by comparing which color space your image is closer to.
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