Two different algorithms. CRC32b is an implementation of the consistency algorithm defined here, whereas CRC32 is the frame check sequence defined here. They're different things, though the differences are not often big.
One way to check this:
<?php
echo hash("crc32", __FILE__)."<br/>";
echo hash("crc32b", __FILE__); ?>
Due to their similarity, the starting hex values will be relatively similar.
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