Cores (or CPUs) are the physical elements of your computer that execute code. Usually, each core has all necessary elements to perform computations, register files, interrupt lines etc.
Most operating systems represent applications as processes. This means that the application has its own address space (== view of memory), where the OS makes sure that this view and its content are isolated from other applications.
A process consists of one or more threads, which carry out the real work of an application by executing machine code on a CPU. The operating system determines, which thread executes on which CPU (by using clever heuristics to improve load balance, energy consumption etc.). If your application consists only of a single thread, then your whole multi-CPU-system won't help you much as it will still only use one CPU for your application. (However, overall performance may still improve as the OS will run other applications on the other CPUs so they don't intermingle with the first one).
Now to your specific questions:
1) The OS usually allows you to at least give hints about on which core you want to execute certain threads. What OpenMP does is to generate code that spawns a certain amount of threads to distribute shared computational work from loops of your program in multiple threads. It can use the OS's hint mechanism (see: thread affinity) to do so.
However, OpenMP applications will still run concurrently to others and thus the OS is free to interrupt one of the threads and schedule other (potentially unrelated) work on a CPU.
In reality, there are many different scheduling schemes you might want to apply depending on your situation, but this is highly specific and most of the time you should be able to trust your OS doing the right thing for you.
2) Even if you are running a single-threaded application on a multi-core CPU, you notice other CPUs doing work as well. This comes a) from the OS doing its job in the meantime and b) from the fact that your application is never running alone -- each running system consists of a whole bunch of concurrently executing tasks. Check Windows' task manager (or ps/top on Linux) to check what is running.
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