Greg, you're almost there--you need (like Moses said) to setup virtual hosts.
So if your Windows hosts file has
127.0.0.1 localhost
127.0.0.1 mysite-dev.com
127.0.0.1 anothersite-dev.com
Your virtual hosts file (httpd-vhosts.conf) might look like:
<VirtualHost *:80>
DocumentRoot C:/xampp/htdocs/
ServerName localhost
</VirtualHost>
<VirtualHost *:80>
ServerName mysite-dev.com
DocumentRoot "C:/sites/mysite-dev"
<Directory "C:/sites/mysite-dev">
Options Indexes FollowSymLinks
AllowOverride All
Order allow,deny
Allow from all
</Directory>
</VirtualHost>
<VirtualHost *:80>
ServerName anothersite-dev.com
DocumentRoot "C:/sites/anothersite-dev"
<Directory "C:/sites/anothersite-dev">
Options Indexes FollowSymLinks
AllowOverride All
Order allow,deny
Allow from all
</Directory>
</VirtualHost>
Don't forget to restart the web server after you make any changes.
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