To preserve NULLs, use CROSS JOIN ... CASE:
select a.ID, b.column_name
, column_value =
case b.column_name
when 'col1' then a.col1
when 'col2' then a.col2
when 'col3' then a.col3
when 'col4' then a.col4
end
from (
select ID, col1, col2, col3, col4
from table1
) a
cross join (
select 'col1' union all
select 'col2' union all
select 'col3' union all
select 'col4'
) b (column_name)
Instead of:
select ID, column_name, column_value
From (
select ID, col1, col2, col3, col4
from table1
) a
unpivot (
column_value FOR column_name IN (
col1, col2, col3, col4)
) b
A text editor with column mode makes such queries easier to write. UltraEdit has it, so does Emacs. In Emacs it's called rectangular edit.
You might need to script it for 100 columns.
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