Referencing an assembly containing a class with extension methods is not enough. You need to import the namespace containing the class in each of your source file where you want to use the extension methods.
For example, to use LINQ-to-objects, you need to reference the System.Core assembly and import the System.Linq namespace (which contains the Enumerable class with the LINQ extension methods):
using System.Linq;
与恶龙缠斗过久,自身亦成为恶龙;凝视深渊过久,深渊将回以凝视…