Hold down the option key, go to Product menu (Xcode 4) and do "Clean Build Folder"... then let off the option key, and do "Clean"...
Now do Product menu > Analyze and make sure all is kosher.
Lastly go to the left hand panel of the project viewer, and click on the icon that represents your entire project. In the window that comes up in the main panel, under "Targets," click on your app. Now click "Build Phases" and expand "Copy Bundle Resources." Make sure that your TouristGuide.xcdatamodeld file is there. Next, expand "Link Binary with Libraries" and make sure that "CoreData.framework" is in there (if you added Core Data to an existing project that didn't start out as a Core Data project, then chances are, it's not in there). Next, expand "Compile Sources" and, of course, double-check that all your model classes are in there (y'know, the NSManagedObject custom sub-classes).
Speaking of those model classes... now click on your TouristGuide.xcdatamodeld and click on the "Default" configuration. Make sure any classes that say "NSManagedObject" in the "Class" column do NOT have custom classes, and if they do list a custom class, make sure you have the equivalently-named .h and .m files corresponding to those.
10-to-1 it's something to do with your model file itself. Onetime I changed my model file's full path (it should be /Users/You/Documents/Developer/MyApp/MyModel.xcdatamodeld/MyModel.xcdatamodel). Once I had changed it, I couldn't figure out how to change it back, because MyModel.xcdatamodeld is a "package" file, not a folder. Sure, in the finder, you can do "Show Package Contents...", but XCode's dialog box for picking the file's location refused to navigate into the package contents! SO I was unable to ever re-select the .xcdatamodel file that resides within the .xcdatamodeld file! I had to totally recreate my entire model file from scratch, it was a huge pain. Maybe there's a way to do it but I couldn't figure it out.
Also, two last tricks.
First last trick, try this on a backup of your project just in case, but it worked for me when I got stuck: change your code from this:
NSURL *modelURL = [[NSBundle mainBundle] URLForResource:@"TouristGuide" withExtension:@"momd"];
to this:
NSURL *modelURL = [[NSBundle mainBundle] URLForResource:@"TouristGuide" withExtension:@"mom"];
...change "momd" to "mom".
Then delete the app from device or simulator, "Clean build folder," "clean," and rebuild and re-run the project. It might give you errors, it might not. After that, then change it back to "momd" and redo all those steps. Changing this will might make XCode delete more stuff than it otherwise would when you do "Clean Build Folder" and reinstall the app. That way it's making a fresh "momd" file when you switch back.
Second last trick:
It also never hurts to #import in your headers, just for good luck. :D
Hope this helps. If someone would have told me this stuff at the beginning it would have saved me a lot of time.