Assuming you want to float the elements, you would also have to float the label
elements too.
Something like this would work:
label {
/* Other styling... */
text-align: right;
clear: both;
float:left;
margin-right:15px;
}
#form {
background-color: #FFF;
height: 600px;
width: 600px;
margin-right: auto;
margin-left: auto;
margin-top: 0px;
border-top-left-radius: 10px;
border-top-right-radius: 10px;
padding: 0px;
text-align:center;
}
label {
font-family: Georgia, "Times New Roman", Times, serif;
font-size: 18px;
color: #333;
height: 20px;
width: 200px;
margin-top: 10px;
margin-left: 10px;
text-align: right;
clear: both;
float:left;
margin-right:15px;
}
input {
height: 20px;
width: 300px;
border: 1px solid #000;
margin-top: 10px;
float: left;
}
input[type=button] {
float:none;
}
<div id="form">
<form action="" method="post" name="registration" class="register">
<fieldset>
<label for="Student">Name:</label>
<input name="Student" id="Student" />
<label for="Matric_no">Matric number:</label>
<input name="Matric_no" id="Matric_no" />
<label for="Email">Email:</label>
<input name="Email" id="Email" />
<label for="Username">Username:</label>
<input name="Username" id="Username" />
<label for="Password">Password:</label>
<input name="Password" id="Password" type="password" />
<input name="regbutton" type="button" class="button" value="Register" />
</fieldset>
</form>
</div>
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