At first you have to mention tomcat up to tomcat's version refer below
CATALINA_HOME: C:Program Filesapache-tomcat-6.0.35;
then set CLASSPATH variable to
CLASSPATH : C:Program Filesapache-tomcat-6.0.35lib;
then finally edit path variable to
PATH: .;%CATALINA_HOME%in;
NOTE: a semicolon(;) must be put at the end of each and every variable.
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