This is possible in XSD 1.1; below is a simplified example, which assumes MainApplicant and WhereSigned are mandatory when CustomerId is equal to zero.
<?xml version="1.0" encoding="utf-8" ?>
<!-- XML Schema generated by QTAssistant/XSD Module (http://www.paschidev.com) -->
<xsd:schema elementFormDefault="qualified" xmlns:xsd="http://www.w3.org/2001/XMLSchema" xmlns:xtm="http://paschidev.com/schemas/metadata/xtm">
<xsd:complexType name="Request">
<xsd:all>
<xsd:element name="UserID" type="xsd:string" />
<xsd:element name="Password" type="xsd:string" />
<xsd:element name="ReferenceNumber" type="xsd:string" minOccurs="0"/>
<xsd:element name="CustomerId" type="xsd:integer"/>
<xsd:element ref="WhereSigned" minOccurs="0"/>
<xsd:element name="ContactName" type="xsd:string" minOccurs="0" />
<xsd:element name="ContactTelephone" type="xsd:string" minOccurs="0" />
<xsd:element name="ContactFax" type="xsd:string" minOccurs="0" />
<xsd:element name="ContactEmail" type="xsd:string" minOccurs="0" />
<xsd:element ref="MainApplicant" minOccurs="0" />
<xsd:element ref="JointApplicant" minOccurs="0" />
<xsd:element ref="Asset" minOccurs="0" />
</xsd:all>
<xsd:assert test="CustomerId[. eq 0] and WhereSigned and MainApplicant or CustomerId[. ne 0]" />
</xsd:complexType>
<xsd:element name="Asset"/>
<xsd:element name="MainApplicant" />
<xsd:element name="JointApplicant" />
<xsd:element name="WhereSigned" />
</xsd:schema>
Minimum valid XML, when CustomerId is zero:
<root xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:type="Request">
<UserID>UserID1</UserID>
<Password>asodasqZX==</Password>
<CustomerId>0</CustomerId>
<WhereSigned/>
<MainApplicant/>
</root>
When CustomerId is non-zero, then this is the minimum XML:
<root xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:type="Request">
<UserID>UserID1</UserID>
<Password>asodasqZX==</Password>
<CustomerId>1</CustomerId>
</root>
The conditional can be easily controlled (see the @test expression); add regular XSD constraints as needed (e.g. if your CustomerId needs to be greater than or equal to zero, then make it nonNegativeInteger, etc.)
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