I would go with Saket's reply. But instead of hardcoding the location its always better to have a relative path.
If you started your application from a main method from a class called Launcher for example and this is the structure of your Eclipse Project directory:
Java Project
src
bin
Then just give your location to be
log4j.appender.R.File=./log/Logfile.log
This will create the file under a directory log:
Java Project
src
bin
log
LogFile.log
Hope you got it..
:)
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