jQuery's Sizzle Engine parse selectors from right to left, so it's true. There are exceptions though, for example when the first operand is an ID. Then the search will operate in the context of the element with this ID. That's a particularity of the Sizzle Engine, but I don't know how querySelectorForAll is implemented.
An example:
$('div.data .gonzalez');
Sizzle will get all the DOM elements with class gonzalez then check for each if an ancestor is a div tag with class data
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